What is the significance of an elevated osmolar gap (osmotic gap) in a patient?

Medical Advisory BoardAll articles are reviewed for accuracy by our Medical Advisory Board
Educational purpose only • Exercise caution as content is pending human review
Article Review Status
Submitted
Under Review
Approved

Last updated: May 27, 2025View editorial policy

Personalize

Help us tailor your experience

Which best describes you? Your choice helps us use language that's most understandable for you.

From the Guidelines

In patients presenting with ethylene glycol poisoning, we recommend extracorporeal treatment (ECTR) if the osmol gap is > 50, as this is associated with a high risk of adverse outcomes and mortality. The osmolar gap is calculated as measured osmolality − calculated osmolarity, in SI units and adjusted for ethanol, and is used as a surrogate to predict the ethylene glycol concentration when assays are not readily available 1.

Key Considerations

  • The osmol gap is a poor screening test for ethylene glycol ingestion at low values, but correlates linearly with ethylene glycol concentration at high levels 1.
  • An osmol gap > 50 is a reasonable criterion for initiating ECTR, especially if there is a confirmed history of ethylene glycol ingestion 1.
  • If no antidote is available, an osmol gap > 10, in the context of ethylene glycol exposure, is also a reasonable criterion for hemodialysis 1.

Calculation and Interpretation

  • The calculated osmolality is determined using the formula: 2 × [Na+] + [glucose]/18 + [BUN]/2.8 + [ethanol]/4.6 (if applicable) 1.
  • The osmolar gap is then calculated by subtracting the calculated osmolality from the measured osmolality obtained from laboratory testing.
  • An elevated osmolar gap (>10 mOsm/kg) suggests the presence of unmeasured osmotically active substances in the blood, which commonly occurs in toxic alcohol ingestions, including ethylene glycol poisoning 1.

Clinical Decision-Making

  • The osmolar gap should be interpreted alongside clinical presentation and other laboratory values, as it may be normal early in toxic alcohol ingestion before significant metabolism occurs or in cases where the toxin has already been metabolized 1.
  • In patients presenting with ethylene glycol poisoning, we suggest ECTR if the osmol gap is 20-50, as this is associated with a moderate risk of adverse outcomes 1.
  • The decision to initiate ECTR should be individualized, taking into account the patient's clinical presentation, laboratory values, and the availability of antidotes 1.

From the Research

Osmolar Gap

  • The osmolar gap is a useful diagnostic tool in clinical practice, particularly in the differential diagnosis of patients presenting with possible drug or substance overdose, as well as in comatose hospitalized patients 2.
  • An increased serum osmolal gap can be an important clue to exposure to toxic alcohols, such as methanol, ethylene glycol, diethylene glycol, propylene glycol, or isopropanol 3.
  • However, other disorders, including diabetic or alcoholic ketoacidosis, acute kidney injury, chronic kidney disease, and lactic acidosis, can also cause high-anion-gap metabolic acidosis associated with an increased serum osmolal gap 3.

Calculation and Interpretation

  • The calculation of osmolal gap is crucial in the differential diagnosis of many patients, and the best formula used for the calculation of osmolal gap should be employed 2.
  • An osmolar gap >10 mosm/kg is considered significant, and this can be observed in critically ill patients with true hyponatremia, particularly in those with severe organ dysfunctions 4.

Clinical Applications

  • Fomepizole, an anti-metabolite therapy, is used to diminish the toxicity from methanol or ethylene glycol, and its elimination kinetics have been well described in healthy human subjects and poisoned patients 5, 6.
  • The use of fomepizole has been shown to be efficacious and well tolerated in pediatric patients with ethylene glycol poisoning, and hemodialysis may not be necessary in most cases if treated with fomepizole 5.
  • The osmolar gap can be useful in monitoring the effectiveness of treatment, as a decrease in plasma osmolar gap has been observed during correction of hyponatremia in patients with an increased osmolar gap 4.

References

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Research

Approach to the evaluation of a patient with an increased serum osmolal gap and high-anion-gap metabolic acidosis.

American journal of kidney diseases : the official journal of the National Kidney Foundation, 2011

Research

Analysis of Fomepizole Elimination in Methanol- and Ethylene Glycol-Poisoned Patients.

Journal of medical toxicology : official journal of the American College of Medical Toxicology, 2022

Related Questions

What medical conditions, medications, or substances can cause a high osmolar gap?
What is the significance of the osmolal gap in a patient with hypernatremia, normoglycemia, and normal Blood Urea Nitrogen (BUN) levels, and an osmolality of 316 mOsm/Kg?
What are the causes of a high osmolar gap?
What is the appropriate treatment for a patient with metabolic acidosis and an elevated anion gap?
What are the implications and treatment for an elevated anion gap of 31.5, indicating anion gap metabolic acidosis?
Are all patients with Klinefelter syndrome (47,XXY) infertile?
What is the differential diagnosis for knee and lower leg swelling and tenderness, also known as edema (excess fluid) and pain in the knee and lower extremity (lower leg)?
Is there evidence for the use of vitamin supplements in children with Autism Spectrum Disorder (ASD) to support cognitive development?
What is the significance of a mildly dilated pancreatic duct without sonographic evidence of a focal pancreatic mass or obstructing etiology, specifically in the context of pancreatic (pancreas) duct dilation?
What are the most likely causes of orthostatic hypotension in a professional soccer player with a pulse of bradycardia (heart rate 47-53 beats per minute) and blood pressure readings indicating a decrease in systolic and diastolic blood pressure when changing from a seated to a standing position?
What is the clinical significance of a 65-year-old male's elevated Prostate-Specific Antigen (PSA) level of 5.0, with a history of high-grade bladder Transitional Cell Carcinoma (TCC), Benign Prostatic Hyperplasia (BPH), and recent Computed Tomography (CT) scan showing prostatomegaly with bladder outlet obstruction?

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

Have a follow-up question?

Our Medical A.I. is used by practicing medical doctors at top research institutions around the world. Ask any follow up question and get world-class guideline-backed answers instantly.