What are the causes of an elevated Anion Gap (AG)?

Medical Advisory BoardAll articles are reviewed for accuracy by our Medical Advisory Board
Educational purpose only • Exercise caution as content is pending human review
Article Review Status
Submitted
Under Review
Approved

Last updated: March 26, 2025View editorial policy

Personalize

Help us tailor your experience

Which best describes you? Your choice helps us use language that's most understandable for you.

From the Guidelines

An elevated anion gap is primarily caused by conditions such as methanol, uremia, diabetic ketoacidosis, lactic acidosis, ethylene glycol, and salicylates, which can be remembered using the mnemonic MUDPILES. The anion gap is calculated as the difference between measured cations (primarily sodium) and measured anions (chloride and bicarbonate) in the blood, and it exceeds the normal range of 8-12 mEq/L in these conditions 1.

Causes of Elevated Anion Gap

  • Methanol poisoning
  • Uremia (kidney failure)
  • Diabetic ketoacidosis
  • Lactic acidosis
  • Ethylene glycol poisoning
  • Salicylate toxicity
  • Other causes such as propylene glycol, isoniazid/iron, and paraldehyde ingestion

Diagnosis and Management

The diagnosis of an elevated anion gap involves calculating the anion gap and identifying the underlying cause. Management includes identifying and treating the underlying cause while supporting vital functions. For toxic ingestions like methanol or ethylene glycol, fomepizole (15 mg/kg loading dose, then 10 mg/kg every 12 hours) or ethanol infusion may be needed to block toxic metabolite formation 1. Sodium bicarbonate (1-2 mEq/kg IV) may be administered for severe acidosis (pH < 7.1) to temporarily stabilize the patient. Hemodialysis is often required for severe cases of toxic alcohol ingestion, uremia, or refractory acidosis.

Clinical Indications for Extracorporeal Treatment

In patients presenting with ethylene glycol poisoning, extracorporeal treatment (ECTR) is recommended if the anion gap is > 27 mmol/L (strong recommendation, very low-quality evidence) and suggested if the anion gap is 23-27 mmol/L (weak recommendation, very low-quality evidence) 1. The anion gap is a useful surrogate marker for glycolate and correlates linearly with glycolate and is associated with clinical outcomes 1.

Key Considerations

Prompt identification and treatment of the underlying cause is essential to prevent serious complications. The elevated anion gap represents accumulation of acids that donate hydrogen ions, causing metabolic acidosis, which can lead to impaired cardiac function, altered mental status, and respiratory compensation through increased breathing rate. Other clinical manifestations such as respiratory failure and pulmonary edema would occur after already stated indications for ECTR 1.

From the Research

Causes of Elevated Anion Gap

The causes of an elevated Anion Gap (AG) can be attributed to various factors, including:

  • Metabolic acidosis, which can be caused by the presence of organic anions such as beta-hydroxybutyrate, acetoacetate, and lactate 2
  • Lactic acidosis, ketoacidosis, and impaired renal function, which are frequent causes of high anion gap metabolic acidosis (HAGMA) 3, 4
  • Severe increases in concentration of phosphorus, which can cause hyperphosphatemic acidosis 4
  • Diabetic ketoacidosis, which can lead to an increased anion-gap caused by the presence of organic anions 2, 4
  • Renal failure, which is a common cause of high AG acidosis 4
  • Sepsis, hyperglycaemia, prior gastric bypass surgery, decreased renal perfusion, and paracetamol intake, which can contribute to the development of HAGMA 3
  • Toxic alcohols, such as methanol, ethylene glycol, diethylene glycol, propylene glycol, or isopropanol, which can cause an increase in serum osmolality and serum osmolal gap with or without high-anion-gap metabolic acidosis 5
  • Diabetic or alcoholic ketoacidosis, acute kidney injury, chronic kidney disease, and lactic acidosis, which can cause high-anion-gap metabolic acidosis associated with an increased serum osmolal gap 5

Common Causes of Increased Anion Gap

The most common causes of increased anion gap include:

  • Hypertensive disease
  • Chronic renal failure
  • Malignant neoplasms
  • Diabetes mellitus
  • Heart diseases 6

References

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Research

[Acid-base balance disorder in various diseases--diabetes mellitus].

Nihon rinsho. Japanese journal of clinical medicine, 1992

Research

A Quick Reference on High Anion Gap Metabolic Acidosis.

The Veterinary clinics of North America. Small animal practice, 2017

Research

Approach to the evaluation of a patient with an increased serum osmolal gap and high-anion-gap metabolic acidosis.

American journal of kidney diseases : the official journal of the National Kidney Foundation, 2011

Research

Update on value of the anion gap in clinical diagnosis and laboratory evaluation.

Clinica chimica acta; international journal of clinical chemistry, 2001

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

Have a follow-up question?

Our Medical A.I. is used by practicing medical doctors at top research institutions around the world. Ask any follow up question and get world-class guideline-backed answers instantly.