What medications are contraindicated in Glucose-6-phosphate dehydrogenase (G6PD) deficiency?

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Medications Contraindicated in G6PD Deficiency

Only seven medications have solid evidence for absolute contraindication in G6PD deficiency: dapsone, methylthioninium chloride (methylene blue), nitrofurantoin, phenazopyridine, primaquine, rasburicase, and tolonium chloride (toluidine blue). 1, 2

Absolutely Contraindicated Medications

High-Risk Oxidant Drugs

  • Dapsone is contraindicated as it is a potent oxidant that causes methemoglobinemia and red blood cell hemolysis by overcoming the reductive capacity of G6PD, with hemolysis and Heinz body formation exaggerated in G6PD-deficient individuals 1, 3

  • Methylene blue (methylthioninium chloride) is absolutely contraindicated as it causes severe hemolytic anemia in G6PD-deficient patients 1, 2

  • Primaquine is contraindicated in severe G6PD deficiency and should only be used in mild to moderate deficiency (>30% to <70% activity) at reduced dosing (45 mg once weekly for 8 weeks) 4, 5

  • Rasburicase is explicitly contraindicated in G6PD-deficient individuals because hydrogen peroxide is a major by-product of uric acid conversion to allantoin, causing hemolysis within 2-4 days of treatment initiation 6

  • Nitrofurantoin, phenazopyridine, and tolonium chloride (toluidine blue) are definitively contraindicated based on evidence of hemolytic risk 1, 2

8-Aminoquinolines

  • Tafenoquine is contraindicated in G6PD deficiency (hemizygous males and homozygous females) and should only be given to those with G6PD activity >70% of the local population median 7

  • Both primaquine and tafenoquine are contraindicated during pregnancy regardless of G6PD status 4

Medications Safe at Normal Therapeutic Doses

Antimalarials

  • Chloroquine and hydroxychloroquine in standard doses appear relatively safe in most G6PD-deficient patients, though monitoring is prudent 1

  • Artemisinin-based combination therapies (ACTs) including artesunate, artemether-lumefantrine, and dihydroartemisinin-piperaquine can be used safely for malaria treatment 4

Commonly Used Medications

  • Benzodiazepines, codeine/codeine derivatives, propofol, fentanyl, and ketamine have not been shown to cause hemolytic crises in G6PD-deficient patients 8

  • Metronidazole and tinidazole are not among the seven definitively contraindicated medications and can be used with appropriate monitoring 9

Critical Clinical Management Principles

Pre-Treatment Screening

  • Screen for G6PD deficiency before starting any oxidant drug in patients of Mediterranean, African, Indian, or Southeast Asian descent 1, 9

  • Qualitative screening is sufficient for males, but quantitative testing is necessary for females to differentiate deficient, intermediate, and normal G6PD status 1, 7

  • Quantitative testing may be needed in borderline cases to determine the degree of deficiency 1

Variant-Specific Risk Stratification

  • Mediterranean variant (Gdmed) typically causes more severe, potentially life-threatening hemolysis and is found predominantly in men from Mediterranean regions, India, and Southeast Asia 1

  • African variant (GdA-) causes milder, self-limited hemolysis and is found in 10-15% of Black men and women 1

Monitoring for Hemolysis

  • Watch for signs of hemolysis including jaundice, dark urine, fatigue, and pallor, particularly within 2-4 days of drug initiation 9, 6

  • Consider baseline hemoglobin measurement before initiating treatment in patients with severe G6PD deficiency or multiple comorbidities 9

  • Immediately and permanently discontinue the offending drug if hemolysis or methemoglobinemia develops, and institute appropriate support measures including potential transfusion support 6

Common Pitfalls to Avoid

  • Do not confuse infection-related hemolytic episodes with drug-induced hemolysis - many compounds have been wrongly cited as causing hemolysis when administered during infections that themselves trigger hemolysis 2

  • Do not assume all antimicrobials are contraindicated - only the seven medications listed above have solid evidence for prohibition 2

  • Do not give tafenoquine or primaquine without quantitative G6PD testing in females - heterozygous females with intermediate activity are at risk for hemolysis 7

  • Avoid confusing G6PD contraindications with those of other conditions - the list is more limited than commonly believed 9

References

Guideline

Medications Contraindicated in G6PD Deficiency

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2025

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Research

Tafenoquine and G6PD: a primer for clinicians.

Journal of travel medicine, 2019

Guideline

Safety of Tinidazole and Metronidazole in Pediatric Patients with G6PD Deficiency

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2025

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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