What is the normal value of ionized calcium (Ionized Ca)?

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Last updated: December 20, 2025View editorial policy

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Normal Value of Ionized Calcium

The normal range for ionized calcium in adults is 1.1–1.3 mmol/L (or 4.6–5.4 mg/dL). 1

Standard Reference Values

  • Ionized calcium concentration normally ranges from 1.1 to 1.3 mmol/L in adults, as established by multiple European trauma guidelines 1
  • When expressed in conventional units, this corresponds to 4.6 to 5.4 mg/dL 1
  • Some sources cite a slightly narrower range of 1.16 to 1.32 mmol/L (4.65 to 5.28 mg/dL) for adults 2
  • The most recent guidelines consistently support the 1.1–1.3 mmol/L range as the standard reference 1

Physiological Context

  • Ionized calcium represents approximately 45-48% of total calcium in extracellular plasma 1
  • The remainder is bound to proteins (40%) or complexed with anions like phosphate, citrate, and bicarbonate (12-15%) 2, 1
  • This free calcium fraction is the physiologically active form essential for cardiac contractility, coagulation, and neuromuscular function 1

Critical pH Dependency

Each 0.1 unit increase in pH decreases ionized calcium concentration by approximately 0.05 mmol/L. 1

  • This occurs because hydrogen ions displace calcium from albumin binding sites, while alkalosis enhances calcium binding to albumin 2, 1
  • You must account for pH changes when interpreting ionized calcium levels, as the measured value is highly pH-dependent 1
  • In patients with acid-base disturbances, actual ionized calcium (not pH-corrected) is the preferred measurement 1

Clinical Thresholds

  • Ionized calcium <0.9 mmol/L requires immediate treatment, particularly in massive transfusion, post-surgical, or critically ill settings 1, 3
  • Levels <0.8 mmol/L are particularly concerning due to increased dysrhythmia risk 3
  • Critical low limits at most medical centers average 0.82 ± 0.14 mmol/L 4
  • Critical high limits average 1.55 ± 0.19 mmol/L at medical centers 4

Common Pitfalls

  • Do not rely solely on total calcium measurements when protein levels are abnormal, as correction formulas have significant limitations 1
  • Laboratory coagulation tests may appear normal despite hypocalcemia because samples are citrated then recalcified before analysis, masking the true impact 1, 3
  • Even mild hypocalcemia impairs the coagulation cascade and platelet function, so borderline values should not be ignored in critically ill patients 1, 3

References

Guideline

Ionized Calcium Guidelines

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2025

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Guideline

Treatment for Severe Hypocalcemia

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2025

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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