How do I calculate serum osmolality for a patient being evaluated for syndrome of inappropriate antidiuretic hormone secretion (SIADH)?

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Serum Osmolality Calculation for SIADH Evaluation

Use the formula: 2 × [Na in mEq/L] + [glucose in mg/dL]/18 + [BUN in mg/dL]/2.8 to calculate serum osmolality when evaluating for SIADH. 1, 2

The Standard Formula

The most widely endorsed calculation across major guidelines is:

Serum Osmolality = 2 × Na (mEq/L) + glucose (mg/dL)/18 + BUN (mg/dL)/2.8

This formula is recommended by:

  • The American Diabetes Association for hyperglycemic crisis evaluation 1
  • The American Academy of Pediatrics for fluid management 1
  • Multiple clinical nutrition societies for hydration assessment 2, 3

Why This Formula Works for SIADH

For SIADH diagnosis specifically, you need to demonstrate hypo-osmolality (<275 mOsm/kg) alongside other criteria. 2, 4

The calculated osmolality helps you:

  • Confirm plasma osmolality <275 mOsm/kg (required for SIADH) 2
  • Rule out hyperglycemia or uremia as causes of altered mental status 1
  • Establish that the hyponatremia is truly hypotonic 2

Alternative Formulas (When to Use Them)

If you need SI units (mmol/L for all values), use: Osmolarity = 1.86 × (Na + K) + 1.15 × glucose + urea + 14 2, 3

This European formula is recommended by Clinical Nutrition societies with a threshold of >295 mmol/L for hyperosmolality. 2 However, for SIADH evaluation in the U.S., stick with the standard formula above using conventional units.

The simplest bedside formula is: 2 × Na + glucose + BUN (all in mmol/L) 5

This Smithline-Gardner formula performs well across different analytical platforms and is useful for rapid mental calculation, though it slightly underestimates osmolality. 5

Critical SIADH Diagnostic Criteria Using Osmolality

Once you calculate serum osmolality, SIADH requires ALL of the following 2, 4:

  • Serum sodium <134 mEq/L
  • Plasma osmolality <275 mOsm/kg (your calculated value)
  • Urine osmolality >500 mOsm/kg (or at minimum >100 mOsm/kg)
  • Urinary sodium >20 mEq/L (often >40 mEq/L)
  • Clinical euvolemia (no edema, no dehydration)

Important Caveats

You must measure actual serum osmolality in addition to calculating it when evaluating SIADH. 2 The difference between measured and calculated osmolality (the osmolal gap) helps identify unmeasured osmoles from toxins or other substances. 6, 5

Verify that glucose and BUN are within normal ranges before attributing abnormal osmolality solely to sodium disturbances. 2, 3 In hyperglycemia, you must correct the sodium value: add 1.6 mEq/L to measured sodium for every 100 mg/dL glucose above 100 mg/dL. 1, 2

Do not rely on clinical signs like skin turgor or mouth dryness to assess volume status in SIADH evaluation—these are highly unreliable. 2 Use objective laboratory values and careful clinical assessment of edema versus dehydration.

Normal Reference Range

Normal serum osmolality is 275-295 mOsm/kg. 1, 2, 3

Values <275 mOsm/kg indicate hypo-osmolality and warrant investigation for SIADH, overhydration, or other causes of hypotonic hyponatremia. 2 Values >300 mOsm/kg indicate hyperosmolality from dehydration or hyperglycemia. 2

References

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Guideline

Serum Osmolality Measurement and Clinical Significance

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2026

Guideline

Plasma Osmolarity Determinants and Calculation

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2026

Research

Harmonisation of Osmolal Gap - Can We Use a Common Formula?

The Clinical biochemist. Reviews, 2016

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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