What are the causes of an increased anion gap (electrolyte imbalance)?

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From the Guidelines

The anion gap is elevated due to accumulation of unmeasured anions in the blood, primarily caused by metabolic acidosis conditions, with the main causes including Methanol, Uremia, Diabetic ketoacidosis, Propylene glycol, Isoniazid/Iron, Lactic acidosis, Ethylene glycol, and Salicylates, as supported by the most recent study 1.

Causes of Increased Anion Gap

The causes of an increased anion gap can be remembered using the mnemonic MUDPILES:

  • Methanol poisoning, which produces toxic metabolites like formic acid and oxalic acid 1
  • Uremia (kidney failure), leading to retention of phosphates, sulfates, and organic acids 1
  • Diabetic ketoacidosis, resulting in accumulation of ketone bodies (acetoacetate and beta-hydroxybutyrate) 1
  • Propylene glycol, Isoniazid/Iron, and other medications or substances that can cause metabolic acidosis 1
  • Lactic acidosis, occurring with tissue hypoxia, sepsis, or liver failure 1
  • Ethylene glycol poisoning, which produces toxic metabolites like glycolate and oxalate 1
  • Salicylate overdose, causing both respiratory alkalosis and metabolic acidosis 1 Other causes include alcoholic ketoacidosis, starvation ketoacidosis, and certain medications like metformin 1.

Anion Gap Calculation

The anion gap represents the difference between measured cations (primarily sodium) and measured anions (chloride and bicarbonate), with normal values typically between 8-12 mEq/L 1. When unmeasured anions increase, the gap widens, reflecting the body's attempt to maintain electroneutrality in the presence of these additional negative charges.

Clinical Implications

The anion gap is a critical parameter in diagnosing and managing metabolic acidosis, and its elevation can indicate serious underlying conditions, such as poisoning or kidney failure 1. Prompt recognition and treatment of the underlying cause are essential to prevent morbidity and mortality.

Key Findings

A recent systematic review and recommendations from the EXTRIP workgroup 1 highlight the importance of considering the anion gap in the diagnosis and management of ethylene glycol poisoning, and provide guidance on the use of extracorporeal treatments in this setting.

Recommendations

In patients with a suspected increased anion gap, it is essential to promptly investigate and address the underlying cause, and to consider the use of extracorporeal treatments, such as hemodialysis, in severe cases, as recommended by the EXTRIP workgroup 1.

From the Research

Causes of Increased Anion Gap

The causes of an increased anion gap can be divided into several categories, including:

  • Lactate accumulation, which can be caused by decreased oxygen delivery or defective oxygen utilization 2
  • Ketoacid production, which can be caused by diabetes, alcohol, or starvation 2, 3
  • Toxin or drug ingestion, such as methanol, ethylene glycol, or salicylates 2, 4, 5
  • Uremia, which can cause a mild acidosis secondary to decreased ammonia secretion and an anion gap caused by the retention of unmeasured anions 2
  • Other causes, such as 5-oxoproline acidosis or starvation ketosis 5, 6

Specific Causes

Some specific causes of increased anion gap include:

  • Diabetic ketoacidosis, which is usually secondary to diabetes 2, 3
  • Alcoholic ketoacidosis, which is usually secondary to alcohol consumption 2, 3
  • Lactation ketoacidosis, which can occur in young and otherwise healthy lactating women who do not meet the high energy requirements of breastfeeding with adequate carbohydrate intake 3
  • Toxic alcohol ingestion, such as methanol or ethylene glycol, which can cause severe acidoses and elevated osmolar gaps 2, 4, 5
  • Salicylate toxicity, which can cause a mild metabolic acidosis and a respiratory alkalosis 2

References

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Research

Anion gap acidosis.

Seminars in nephrology, 1998

Research

Severe lactation ketoacidosis presenting as a respiratory complaint.

Journal of the American College of Emergency Physicians open, 2022

Research

Approach to the evaluation of a patient with an increased serum osmolal gap and high-anion-gap metabolic acidosis.

American journal of kidney diseases : the official journal of the National Kidney Foundation, 2011

Research

Use of anion gap in the evaluation of a patient with metabolic acidosis.

American journal of kidney diseases : the official journal of the National Kidney Foundation, 2014

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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