What are Angiotensin-Converting Enzyme (ACE) inhibitors?

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Angiotensin-Converting Enzyme (ACE) Inhibitors

ACE inhibitors are medications that inhibit the angiotensin-converting enzyme, blocking the conversion of angiotensin I to angiotensin II, resulting in vasodilation, decreased aldosterone secretion, and reduced blood pressure, with proven benefits in hypertension, heart failure, and diabetic nephropathy. 1, 2, 3

Mechanism of Action

ACE inhibitors work through several key mechanisms:

  • Inhibit the enzyme that converts angiotensin I to angiotensin II (a potent vasoconstrictor)
  • Decrease aldosterone secretion from the adrenal cortex
  • Prevent the degradation of bradykinin (a vasodilator)
  • Reduce vasopressor activity and promote vasodilation
  • Suppress the renin-angiotensin-aldosterone system (RAAS) 2, 3

These effects lead to:

  • Decreased systemic vascular resistance
  • Reduced blood pressure
  • Improved cardiac output
  • Natriuresis (increased sodium excretion)
  • Small increases in serum potassium

Types and Pharmacokinetics

ACE inhibitors differ in their chemical structure, potency, bioavailability, and pharmacokinetic properties:

ACE Inhibitor Initial Dose Maximum Dose Dosing Frequency Distinctive Characteristics
Captopril 6.25 mg 50 mg TID 3 times/day Rapid and short-acting, contains sulfhydryl group
Enalapril 2.5 mg 10-20 mg BID 2 times/day Prodrug requiring hepatic activation
Lisinopril 2.5-5 mg 20-40 mg 1 time/day Not a prodrug, renal elimination
Ramipril 1.25-2.5 mg 10 mg 1 time/day Higher lipophilicity, good tissue penetration
Perindopril 2 mg 8-16 mg 1 time/day High tissue affinity
Trandolapril 1 mg 4 mg 1 time/day Long half-life

1

Key pharmacokinetic differences:

  • Captopril and lisinopril are the only ACE inhibitors that are not prodrugs
  • Most ACE inhibitors are eliminated primarily through the kidneys
  • Lisinopril is the only ACE inhibitor that doesn't require hepatic metabolism
  • ACE inhibitors vary in their lipophilicity and tissue penetration 1, 2, 3

Clinical Applications

ACE inhibitors are indicated for several cardiovascular and renal conditions:

  1. Heart Failure with Reduced Ejection Fraction (<40%):

    • Reduce mortality and hospitalizations
    • Improve symptoms and functional capacity
    • Should be prescribed to all eligible patients 1
  2. Hypertension:

    • Particularly effective in patients with diabetes, heart failure, or kidney disease
    • Target blood pressure <130/80 mmHg in diabetic patients 1, 2
  3. Post-Myocardial Infarction:

    • Reduce ventricular remodeling and cardiovascular mortality 1
  4. Diabetic Nephropathy:

    • Delay progression of renal disease 4, 1

Adverse Effects

Common adverse effects include:

  • Dry Cough: Occurs in up to 20% of patients due to bradykinin accumulation
  • Angioedema: Rare (<1%), more common in African Americans and women
  • Hypotension: More frequent at treatment initiation and in volume-depleted patients
  • Hyperkalemia: Approximately 15% of patients may experience increases in potassium >0.5 mEq/L
  • Renal Function Deterioration: Particularly in patients with bilateral renal artery stenosis or dehydration 4, 1

Contraindications

  • Absolute: History of angioedema with ACE inhibitors, bilateral renal artery stenosis, pregnancy, anuric renal failure
  • Relative: Systolic blood pressure <80 mmHg, serum creatinine >3 mg/dL, serum potassium >5.5 mEq/L 1

Monitoring Recommendations

  • Check baseline renal function, potassium, and blood pressure before initiating therapy
  • Monitor renal function and potassium 1-2 weeks after initiation, after each dose increase, and at 3-6 month intervals during maintenance
  • Evaluate blood pressure regularly, especially in high-risk patients 4, 1

Special Considerations

  • ACE inhibitors can cause functional acute renal failure, especially in patients with:

    • Extracellular fluid volume depletion
    • Bilateral renal artery stenosis
    • Stenosis of a dominant or single kidney
    • Preexisting hypotension 4
  • ACE inhibitors are less effective as monotherapy in Black hypertensive patients (typically a low-renin population) 2, 3

  • When ACE inhibitors cannot be tolerated due to cough, angiotensin receptor blockers (ARBs) are a reasonable alternative with similar efficacy but fewer side effects 1

References

Guideline

Treatment of Cardiovascular Diseases with ACE Inhibitors

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2025

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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