What is the concentration in millimoles per litre of a 3 % sodium chloride solution (100 mL)?

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Sodium Concentration in 3% NaCl Solution

A 3% sodium chloride solution contains 513 mmol/L of sodium (or 513 mEq/L).

Calculation Method

To determine the sodium concentration in any NaCl solution, use the following approach 1:

  • 3% NaCl means 3 grams of NaCl per 100 mL of solution 1
  • Molecular weight of NaCl = 58.5 g/mol 1
  • Calculation: (3 g / 58.5 g/mol) × (1000 mL / 100 mL) = 513 mmol/L 1

Since sodium chloride dissociates 1:1 into sodium and chloride ions, this equals 513 mmol/L of sodium and 513 mmol/L of chloride 1.

Clinical Context for 3% Hypertonic Saline

Primary Indication

  • 3% hypertonic saline is indicated for severe symptomatic hyponatremia with neurological manifestations such as seizures, altered mental status, or coma 1, 2

Standard Dosing Protocol

  • Administer 100 mL boluses of 3% NaCl intravenously over 10 minutes, repeating up to three times at 10-minute intervals for severe symptomatic hyponatremia 1
  • Target an initial correction of 6 mmol/L over 6 hours or until severe symptoms resolve 1
  • Never exceed 8 mmol/L correction in any 24-hour period to prevent osmotic demyelination syndrome 1

Alternative Continuous Infusion

  • A continuous infusion of 500 mL of 3% NaCl over 6 hours through a peripheral vein has been shown effective in reversing hyponatremic encephalopathy without producing cerebral demyelination 2
  • In one case series of 71 episodes, this protocol increased mean serum sodium from 114.1 mEq/L to 117.9 mEq/L at 3 hours and 128.3 mEq/L at 48 hours, with marked symptom improvement in 97% of cases 2

Safety Considerations

  • Peripheral administration of 3% saline is safe, with low complication rates: infiltration 3.3%, phlebitis 6.2%, erythema 2.3%, edema 1.8%, and venous thrombosis 1% 1
  • Monitor serum sodium every 2 hours during initial correction for severe symptoms 1
  • High-risk patients (advanced liver disease, alcoholism, malnutrition) require even more cautious correction at 4-6 mmol/L per day maximum 1

Comparison to Other Solutions

  • Normal saline (0.9% NaCl) contains 154 mmol/L sodium, making it truly isotonic 1
  • 0.45% NaCl (half-normal saline) contains 77 mmol/L sodium 3
  • 3% NaCl is markedly hypertonic at 513 mmol/L, approximately 3.3 times the concentration of normal saline 1

References

Guideline

Management of Sodium Imbalance

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2026

Research

Treatment of hyponatremic encephalopathy with a 3% sodium chloride protocol: a case series.

American journal of kidney diseases : the official journal of the National Kidney Foundation, 2015

Guideline

Calculating Water Deficit and D5W Requirements for Hypernatremia

Praxis Medical Insights: Practical Summaries of Clinical Guidelines, 2026

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

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