Are millimoles (mmol) and milliequivalents (meq) the same?

Medical Advisory BoardAll articles are reviewed for accuracy by our Medical Advisory Board
Educational purpose only • Exercise caution as content is pending human review
Article Review Status
Submitted
Under Review
Approved

Last updated: April 22, 2025View editorial policy

Personalize

Help us tailor your experience

Which best describes you? Your choice helps us use language that's most understandable for you.

From the Guidelines

Yes, mmol and mEq can be considered the same for monovalent ions like potassium, as 1 mmol/L is equivalent to 1 mEq/L, as stated in the expert consensus document on the management of hyperkalaemia 1. When considering the measurement of potassium levels in the body, it's essential to understand the units used.

  • A millimole (mmol) represents the amount of a substance containing a specific number of molecules, while a milliequivalent (mEq) represents the chemical combining or reacting power of a substance, taking into account its valence or charge.
  • For monovalent ions like potassium (K⁺), the number of millimoles is equal to the number of milliequivalents, as these ions have a single charge.
  • The study 1 mentions that hyperkalaemia is defined as serum or plasma K+ > 5 mmol/L, and also states that 1 mmol/L = 1 mEq/L, highlighting the equivalence of these units for potassium.
  • This equivalence is crucial in clinical practice, particularly when interpreting laboratory values and calculating electrolyte replacement, to ensure proper patient care and avoid dosing errors.
  • The distinction between mmol and mEq becomes significant for divalent ions, but for potassium, the two units can be used interchangeably, as supported by the expert consensus document 1.

From the Research

Definition of mmol and meq

  • mmol (millimole) is a unit of measurement for the amount of a substance, typically used to express the concentration of a solution.
  • meq (milliequivalent) is a unit of measurement for the amount of a substance that can combine with or replace a certain amount of another substance, typically used to express the concentration of ions in a solution.

Relationship between mmol and meq

  • The relationship between mmol and meq depends on the valence of the ion being measured. For monovalent ions (e.g. sodium, potassium), 1 mmol is equal to 1 meq.
  • For divalent ions (e.g. calcium, magnesium), 1 mmol is equal to 2 meq.
  • In the study 2, hyponatremia is defined by a serum sodium level of less than 135 mEq/L, which is equivalent to less than 135 mmol/L for sodium, a monovalent ion.

Use of mmol and meq in clinical practice

  • Both mmol and meq are used in clinical practice to express the concentration of electrolytes in the blood, as seen in the studies 3, 4, and 5.
  • The study 6 discusses the use of the anion gap, which is calculated using the concentrations of ions in mmol/L, to diagnose and evaluate metabolic acidosis.

Conversion between mmol and meq

  • To convert between mmol and meq, the valence of the ion must be known. For example, to convert mmol of calcium to meq, multiply the number of mmol by 2, since calcium is a divalent ion.
  • The study 4 discusses the reference range for serum magnesium in mmol/L, and also provides the equivalent range in mg/dL.

References

Guideline

Guideline Directed Topic Overview

Dr.Oracle Medical Advisory Board & Editors, 2025

Research

Potassium, magnesium, and electrolyte imbalance and complications in disease management.

Clinical and experimental hypertension (New York, N.Y. : 1993), 2005

Research

The major electrolytes: sodium, potassium, and chloride.

Journal of intravenous nursing : the official publication of the Intravenous Nurses Society, 1994

Research

Update on value of the anion gap in clinical diagnosis and laboratory evaluation.

Clinica chimica acta; international journal of clinical chemistry, 2001

Professional Medical Disclaimer

This information is intended for healthcare professionals. Any medical decision-making should rely on clinical judgment and independently verified information. The content provided herein does not replace professional discretion and should be considered supplementary to established clinical guidelines. Healthcare providers should verify all information against primary literature and current practice standards before application in patient care. Dr.Oracle assumes no liability for clinical decisions based on this content.

Have a follow-up question?

Our Medical A.I. is used by practicing medical doctors at top research institutions around the world. Ask any follow up question and get world-class guideline-backed answers instantly.